Corrigendum: Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal-organic frameworks.

نویسندگان

  • Dawei Feng
  • Kecheng Wang
  • Zhangwen Wei
  • Ying-Pin Chen
  • Cory M Simon
  • Ravi K Arvapally
  • Richard L Martin
  • Mathieu Bosch
  • Tian-Fu Liu
  • Stephen Fordham
  • Daqiang Yuan
  • Mohammad A Omary
  • Maciej Haranczyk
  • Berend Smit
  • Hong-Cai Zhou
چکیده

Metal-organic frameworks with high stability have been pursued for many years due to the sustainability requirement for practical applications. However, researchers have had great difficulty synthesizing chemically ultra-stable, highly porous metal-organic frameworks in the form of crystalline solids, especially as single crystals. Here we present a kinetically tuned dimensional augmentation synthetic route for the preparation of highly crystalline and extremely robust metal-organic frameworks with a preserved metal cluster core. Through this versatile synthetic route, we obtain large single crystals of 34 different iron-containing metal-organic frameworks. Among them, PCN-250(Fe2Co) exhibits high volumetric uptake of hydrogen and methane, and is also stable in water and aqueous solutions with a wide range of pH values.

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عنوان ژورنال:
  • Nature communications

دوره 5  شماره 

صفحات  -

تاریخ انتشار 2014